Solid milk and method of making the same

ABSTRACT

The present invention is based on knowledge that basically, solid milk provided with both of adequate strength and solubility can be obtained by using only powdered milk as ingredient to be provided with compression molding under state where the porosity and the free fat is controlled within predetermined ranges, and then humidified and dried. Namely, solid milk having porosity of 30%-60%, and method of making solid milk including: a compression step for compressing powdered milk to obtain a solid form of compressed powdered milk; a humidifying step for humidifying the compressed powdered milk obtained by the compression step; and a drying step for drying the compressed powdered milk humidified by the humidifying step achieves the object of providing solid milk having preferred solubility and strength, and method of making the same.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application Ser. No.12/158,180, tiled on Jun. 19, 2008, which is a National Stage ofInternational Application No. PCT/JP2006/326394, filed on Dec. 27, 2006,which claims priority to JP2005-379014 filed on Dec. 28, 2015. Thecontents of the priority applications are incorporated by reference intheir entirety.

BACKGROUND OF THE INVENTION

Field of the Invention

The present invention relates to solid milk to be dissolved in heatedwater for drinking, and method of making the same. More specifically,the present invention relates to solid milk having preferred solubilityand strength.

Description of the Related Art

Powdered milk is food product whose shelf life is improved by removingalmost all of the necessary moisture for the microbial growth frombovine milk and the like. Since the capacity and weight decrease byremoving moisture, the powdered milk can be easily transported. Thus,the powdered milk has advantages in shelf life and transportation. Thepowdered milk has interspaces between milk powders, and the porosity ofthe milk powder is generally 60%-70%, so that it readily dissolves inheated water. However, the powdered milk requires measurement of properquantity every time it is dissolved in heated water or the like. Also,upon measurement of the powdered milk or upon taking out the powderedmilk, the powdered milk may spread. Therefore, solid milk that is thepowdered milk made into solid state has been proposed (Japanese UtilityModel Application Laid-Open Publication No. SHO49-130189 (see patentdocument 1 below), and Japanese Utility Model Application Laid-OpenPublication No. SHO61-118280 (see patent document 2 below). However, ithas not been easy to actually make the powdered milk into solid stateand satisfy both of the strength and the solubility. Namely, even if thepowdered milk is made into solid state, it has been easy to break andhas been hard to handle. Moreover, the solid milk has smaller surfacearea compared to the powdered milk, so that it has been less soluble inthe heated water.

When the powdered milk is actually pressured to be made into solidstate, since the powdered milk is an emulsified substance, theemulsified state is destroyed by the pressure. Then the fat called “freefat” oozes from the powdered milk. The free fat readily oxidizes anddestroys flavor of the powdered milk. Also, when the powdered milk isdissolved in the heated water, there is problem that excessive free fatfloats on the water and aggregates. (This phenomenon is called “oiloff”.) On the other hand, the Japanese Examined Patent ApplicationPublication No. SHO49-4948 (see patent document 3 below) discloses“aggregated powdered milk”. The point that “the aggregated powdered milkis easily immersed and thus easily disintegrated when thrown into heatedwater to be dispersed and dissolved” is disclosed. However, the“aggregated powdered milk” in the publication is a mixture with sugar orglucose, so that it is “suitable for use in addition to coffee, tea, orthe like”. Namely, the basic ingredient of the aggregated powdered milkis not only the powdered milk and it is not substituted for breast milkto be given to infants. The Japanese Examined Patent ApplicationPublication No. SHO49-4948, considers the problems of the free fat andthe like when only the powdered milk is used as the basic ingredient,thereby using the mixture of granulated powdered milk and sugar orglucose to make “aggregated powdered milk”. The powdered milk in agranulated state has a larger surface area compared to that in the solidstate, so that its solubility is high even if the porosity of thegranule itself is small.

The Japanese Examined Patent Application Publication No. SHO45-39018(see patent document 4 below) discloses a technology similar to that ofthe above-mentioned Japanese Examined Patent Application Publication No.SHO49-4948. Namely, it is disclosed that in order to achieve readilysoluble solid milk, the volume of interstice may be enlarged, and thatthere is problem of the free fat upon making the powdered milk intosolid state. However, in the same document, since “there is a limit tothe enlargement of a single particle of powdered milk” (column 2, line30 of the same document), “the powdered milk is attached to sugar groupfor granulation and then molded and dried”, whereby “readily solublesolid milk with less free fat” is obtained (column 3, lines 13-15 of thesame document). Namely, in the same document it is mentioned that thesolid milk with only the powdered milk made into solid state cannot beobtained. Moreover, the solid milk described in the reference isobtained by attaching the sugar group to the powdered milk, so that thesugar group as a center core exists and the porosity is reduced. Also,the compositionally-homogeneous solid milk cannot be obtained.

The Japanese Examined Patent Application Publication No. SHO53-59066discloses “solid milk tablet”. This solid milk tablet is a tablet of ahigh density having its fat component leached out on the surface andblocked from external air by the coating of the fat. Since high densitytablet is desirable as the solid milk of the same document, its porosityis low.

Japanese patent No. 3044635 discloses “frozen milk”. The frozen milkincludes a lot of water molecules, so that there is almost no air space.

Also, in the field of food product such as soup, solid food products tobe dissolved by pouring hot water are known (Japanese Patent ApplicationLaid-Open Publication No. HEI11-127823, Japanese Patent ApplicationLaid-Open Publication No. 2004-49220, and Japanese Patent ApplicationLaid-Open Publication No. 2004-49221) to which disintegrant is generallyadded. Also, since ingredients thereof are not the powdered milk, thereis no problem such as free fat that is specific to the powdered milk.Namely, although the solid soup and the like are known, solid milkcannot be obtained by merely diverting these technologies in making thesolid milk since the powdered milk that is the basic ingredient of thesolid milk include a lot of fat.

Also, in the field of medicine, various “intraoral fast disintegrabletablets” readily soluble in the mouth have been developed (e.g. JapanesePatent Application Laid-Open Publication No. HE15-271054, JapanesePatent Application Laid-Open Publication No. HE18-291051, JapanesePatent Application Laid-Open Publication No. HE109-048726, JapanesePatent Application Laid-Open Publication No. 2000-95674, Japanese PatentApplication Laid-Open Publication No. 2000-44463, Japanese PatentApplication Laid-Open Publication No. 2001-89398, Japanese PatentApplication Laid-Open Publication No. 2004-049220, and Japanese PatentNo. 2650493). However, composition of medicine in general has a smallrate in weight occupied by an active substance, so that a lot ofadditives such as vehicle other than the active substance can beblended, and the component design is relatively easy. Therefore,medicine, in general has a high strength, and needless to control itssolubility by controlling the porosity. Also, medicine does not includea lot of fat as the powdered milk. Therefore, “fast disintegrable”technology in the “intraoral fast disintegrable tablet” cannot bediverted as is to the solid milk. Also, “intraoral fast disintegrabletablet” needs to dissolve rapidly by minimal water in the oral cavity.On the other hand, the solid milk is generally dissolved in heated waterfor drinking, but not taken directly into the mouth, so that fastsolubility is not required as much as the “intraoral fast disintegrabletablet”.

[Patent document 1] Japanese Utility Model Application Laid-OpenPublication No. SHO49-130189

[Patent document 2] Japanese Patent Application Laid-Open PublicationNo. SHO61-118280

[Patent document 3] Japanese Examined Patent Application Publication No.SHO49-4948

[Patent document 4] Japanese Examined Patent Application Publication No.SHO45-39018

SUMMARY OF THE INVENTION

An object of the present invention is to provide solid milk having apreferred solubility and strength, and method of making the same.

Another object of the present invention is to provide solid milk that iseasy to handle in transportation and easy to measure, and method ofmaking the same.

Another object of the present invention is to provide solid milk havingsmall degradation of flavor and time degradation such as oil off causedby free fat, and method of making the same.

Another object of the present invention is to provide solid milk whosecomponent composition is controllable with only nutritional component,and method of making the same. Specifically, an object of the presentinvention is to provide solid milk having preferred solubility andstrength without adding additives, and method of making the same.

Another object of the present invention is to provide method of makingsolid milk from powdered milk as is without adding additives such aslubricant.

Mother object of the present invention is to provide method of makingsolid milk which can avoid situation where the powdered milk is attachedto a pestle and a mortar of a compression molding machine in amanufacturing process.

Another object of the present invention is to provide method of makingpowdered milk and solid milk which can make not only the powdered milkbut also the solid milk based on the powdered milk after making thepowdered milk.

The present invention is based on knowledge that basically, solid milkprovided with both of adequate strength and solubility can be obtainedby using only powdered milk as ingredient to be provided withcompression molding under a state where the porosity and the free fat iscontrolled within predetermined ranges, and then humidified and dried.At least one of the above-mentioned objects can be solved by thefollowing solid milk and the method of making the same.

-   [1] One aspect of solid milk of the present invention is solid milk    having porosity of 30%-60%. As described above, proposals for making    solid milk have been made since around the late forty's of the Showa    era. However, there is problem that hard solid milk is    slightly-soluble while solid milk with high solubility is fragile.    Therefore, solid milk satisfying both of the hardness and the    solubility could not be obtained. The present inventors made solid    milk having a porosity of 30%-60% for the first time by controlling    conditions such as the porosity, the fat content or water content    within the basic ingredient, the compression force, the compression    speed, the compression retention time (time to retain the maximum    compression displacement), the amount of free fat, the humidifying    condition, and the drying condition to make the solid milk. The    solid milk thus made is provided with the hardness and the    solubility. Namely, since the solid milk of the present invention    has the porosity of 30%-60%, the required hardness in manufacturing    and distribution and the required solubility at the point of use can    he obtained.-   [2] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein fat content of the    solid milk is equal to or more than 5% by weight. It is to be noted    that “fat content” means percentage of the fat in the weight of the    entire solid milk. As a more specific example of “equal to or more    than 5% by weight” of the fat content, 5%-70% by weight can be    mentioned as will be described later.-   [3] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein emulsified fat and    free fat are included as fat, and free fat content is 0.5%-4% by    weight. As will be described later, the solid milk of the present    invention proactively includes the free fat which has been regarded    preferable not to be generated, thereby obtaining solid milk having    a predetermined interstice.-   [4] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein water content is 1%-4%    by weight.-   [5] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein volume of the solid    milk is 1 cm³-50 cm³. The solid milk of the present invention has    larger volume compared to the conventional powdered milk since it is    solid milk, so that adequate quantity can be easily measured and the    transportation is convenient.-   [6] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein powdered milk is used    as basic ingredient, and composition of the solid milk is    homogeneous. Since predetermined powdered milk such as including    free fat is used as the basic ingredient, solid milk composed of    only the powdered milk can be made without forming a core or the    like with sugar.-   [7] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein only powdered milk is    used as basic ingredient. By using only the powdered milk as the    basic ingredient, the compositionally-homogeneous solid milk can be    easily obtained.-   [8] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein when a particle of the    solid milk is put into 100 ml of water at 50° C., time required for    the solid milk to completely dissolve is 5 sec-60 sec on vibrating    condition of 1.5 laps/s and amplitude of 30 cm, Having a    predetermined porosity, the solid milk of the present invention has    fast solubility, thereby satisfying the requirements of the    marketplace as commercial product.-   [9] Another aspect of the solid milk of the present invention is the    solid milk as described in [1] above, wherein the power at the time    of breaking the sample by applying load in a direction which    minimizes an area of a broken-out section is 20N-300N. The solid    milk of the present invention has a certain degree of hardness so    that a situation where the solid milk breaks during transportation    can be prevented to some extent. It is to be noted that another    aspect of the solid milk of the present invention is the solid milk    having the porosity of 30%-60%, the fat content of 5%-70% by weight,    the free fat content of 0.5%-4% by weight of the entire solid milk,    the water content of 1%-4% by weight, the volume of 1 cm³-50 cm³,    and only the powdered milk used as the basic ingredient. The solid    milk adopting such composition has the fast solubility as indicated    by [8] above and the above-mentioned degree of hardness.-   [10] One aspect of a method for making solid milk of the present    invention is a method of making solid milk including: a compression    step for compressing powdered milk to obtain a solid form of a    compressed powdered milk; a humidifying step for humidifying the    compressed powdered milk obtained by the compression step; and a    drying step for drying the compressed powdered milk humidified by    the humidifying step; wherein a compression force in the compression    step is 50 KPa-30 MPa.-   [11] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10] above, wherein substantially no additive is added in the    compression step.-   [12] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10] above, wherein powdered milk whose fat content is equal to or    more than 5% by weight is used in the compression step,-   [13] Mother aspect of the method of making solid milk of the present    invention is the method of making solid milk as described in [10]    above, wherein free fat content of the compressed powdered milk is    0.5%-4% by weight. In the method of making solid milk of the present    invention, by proactively including the free fat which have been    regarded preferable not to be generated, solid milk having a    predetermined interstice is obtained.-   [14] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10], wherein the compression force in the compression step is    controlled so that porosity of the compressed powdered milk assumes    30%-60%.-   [15] Mother aspect of the method of making solid milk of the present    invention is the method of making solid milk as described in [10],    wherein the compression step obtains the solid form of the    compressed powdered milk by using a compression molding machine to    compress the powdered milk and compression speed of the compression    molding machine is 0.1 mm/s-100 mm/s. As will be verified in the    embodiments described later, when the compression speed (mobile    speed of pestle) is small, while it takes time to make the powdered    milk solid, solid milk having high porosity, as well as high    hardness and excellent solubility can be obtained. Therefore, in the    above-mentioned range of compression speed, the desirable solid milk    can be obtained. As will be shown by the embodiments described    later, when the porosity is large (e.g. exceeding 50%), the    solubility was improved while maintaining predetermined hardness by    keeping the compression speed 0.1 mm/s-40 mm/s. On the other hand,    when the porosity is small (e.g. 50% or less), predetermined    solubility was achieved while maintaining predetermined hardness    even if the compression speed is made approximately 100 mm/s.-   [16] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10], wherein compression retention time (time to retain the maximum    compression displacement) in the compression step is 0.1 sec-1 min-   [17] Mother aspect of the method of making solid milk of the present    invention is the method of making solid milk as described in [10],    wherein amount of moisture added to the compressed powdered milk is    0.5%-3% by weight of the compressed powdered milk after the    compression step.-   [18] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10], wherein humidifying time in the humidifying step is 5 sec-1    hour.-   [19] Another aspect of the method of making solid milk of the    present invention is the method of making solid milk as described in    [10], wherein water content of the solid milk is controlled within    1% more or less than water content of the powdered milk used as the    ingredient.

In this specification, “porosity” means a percentage of the volume ofinterstices accounting for the volume of powder mass (see e.g. “Iyakuhinno Kaihatu (Development of Medicine)” edited by Miyajima Kouichiro(Vol.15), Hirokawa Shoten 1989, Page 240). More specifically, it is avalue measured by “porosity measurement for solid milk” in a testexample which will be described later.

In this specification, “powdered milk” means modified milk and the likewhich is dried and powdered mixture of fat-soluble component such asmilk fat and resin and water-soluble component such as water, sugar,protein (including peptide and amino acid), and mineral. Examples ofpowdered milk include whole milk powder, modified milk powder, creamypowder, and the like.

In this specification, “solid milk” means a type of milk modified intosolid state at normal temperature. The solid milk specifically meanspowdered milk molded into a predetermined size and size and weight,which renders, when dissolved in water, the same substance as that ofthe powdered milk dissolved in water.

In this specification, “compositionally-homogeneous” means to havesubstantially the same composition in all parts of the solid milk. It isto be noted that cases where components unintended for addition ofsolidness and solubility are added and mixed before compression moldingare also “compositionally-homogeneous”. However, the states in which thepowdered milk having small grain diameter is attached to the sugar grouphaving large grain diameter as core, for example as in the patentdocument 3 or the patent document 4 cannot be called“compositionally-homogeneous”. Whereas in a case where coating layer isprovided on the surface after making the solid milk, since the interiorof the coating layer is the solid milk and the solid milk may be called“compositionally-homogeneous”.

In this specification, “additive” means an agent or agents such asbinder, disintegrant, lubricant, and leaven other than nutritionalcomponent

In this specification, “substantially no additive is added” means to usebasically only the powdered milk as the basic ingredient, where theadditive is equal to or less that 0.5% by weight (preferably 0.1% byweight or less) that is the amount that the additive has no effect onthe nutritional component. It is to be noted that in the presentinvention, it is preferable that only the powdered milk is used as thebasic ingredient and that no additive other than the powdered milk isused.

EFFECT OF THE INVENTION

According to the present invention, porosity of solid milk iscontrolled, so that solid milk having preferred solubility and strength,and method of making the same can be provided.

According to the present invention, solid milk has a predetermined shapeand size, so that solid milk that is easy to handle in transportationand easy to measure, and method of making the same can be provided.

According to the present invention, free fat that is deemed to be thecause of degradation of flavor resulting from oxidization degradation offat while the powdered milk is preserved is intentionally generatedwithin trouble-free range. Thus, by efficiently utilizing the free fatas lubricant or the like, solid milk having little degradation of flavorand the time degradation caused by free fat, and method of making thesame can be provided without adding an additive.

According to the present invention, the powdered milk can be made intosolid milk as is, so that solid milk whose component composition iscontrollable with only nutritional component by controlling thecomposition of the powdered milk itself, and method of making the samecan be obtained.

According to the present invention, a situation where the powdered milkis attached to a pestle and a mortar of a compression molding machinecan be avoided by controlling rate of free fat in the powdered milk,porosity and amount of water (especially the free fat) within suitablerange, thereby providing highly productive method of making solid milk.

According to the present invention, the free fat can be utilizedeffectively as substitute for an additive as described above, so thatmethod of making solid milk from powdered milk as is without addingadditives such as lubricant to the powdered milk can be provided.

According to the present invention, method of making powdered milk andsolid milk which can manufacture not only the powdered milk but also thesolid milk based on the powdered milk after manufacturing the powderedmilk can be provided.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a graph showing relationship between porosity and dissolutiontime in embodiment 1;

FIG. 2 is a graph showing relationship between compression force andfree fat in embodiment 1;

FIG. 3 is a graph showing relationship between humidification time andstrength in embodiment 5;

FIG. 4 is a graph showing relationship between humidifying water amountand hardness in embodiment 5;

FIGS. 5A-5C are graphs showing physicality of solid milk obtained by anembodiment 8. FIG. 5A is a graph showing relationship betweencompression speed and hardness of the obtained solid milk. FIG. 5B is agraph showing relationship between compression speed and free fat. FIG.5C is a graph showing relationship between hardness and free fat ofsolid milk; and

FIGS. 6A and 6B are graphs showing physicality of solid milk obtained byan embodiment 9. FIG. 6A is a graph showing relationship betweencompression speed and hardness of the obtained solid milk. FIG. 6B is agraph showing relationship between compression speed and free fat; and

FIG. 7 is a graph showing physicality of solid milk obtained byembodiment 10.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

1. Solid Milk

The solid milk of the present invention has porosity of 30%-60% (between30% and 60% inclusive). As the porosity increases the solubilityincreases but the strength decreases. Also, when the porosity is small,the solubility is low. The porosity is mainly controlled by thecompression force in the compression process. It is to be noted that inthe present invention, while the porosity may be 35%-50%, the porositymay be adjusted to 30%-35%, 30%-45%, 40%45%, or 40%-50%, according toits intended purpose. Also, as proven by embodiments which will bedescribed later, even if the solid milk has high porosity, one withexcellent solubility and hardness can be obtained by appropriatelyadjusting the porosity, the fat content or water content within thebasic ingredient, the compression force, the compression speed, thecompression retention time (time to retain the maximum compressiondisplacement), the amount of free fat, the humidifying condition, andthe drying condition. Therefore, as preferable porosity of the solidmilk in the present invention, more than 50% and equal to or less than65% can be mentioned while more than 50% and equal to or less than 60%,more than 50% and equal to or less than 58%, more than 50% and equal toor less than 55% are also applicable. Also, the porosity may be 55%-65%, 55%-60%, or 55%-58%. By adjusting the porosity to be within theseranges, it is made possible to obtain favorable solid milk havingresolved the problems of an oil off and the like as will be describedlater.

It is preferable that plurality of interstices exist in solid milk. Theinterstices (hollows) are preferably distributed evenly. Since theinterstices are distributed almost evenly in the solid milk, highersolubility can be obtained. The larger the interstice, the easier thewater can penetrate, so that fast solubility can be obtained. On theother hand, when the size of the interstice is too big, the strength isdecreased or the surface of the solid milk becomes rough. Therefore, asthe size of the interstice, 10 μm-500 μm can be mentioned while 50μm-300 μm is preferable. This size of the interstice can be measuredwith known means, such as an examination of the surface and thecross-section plane of the solid milk by using a scanning electronmicroscope.

The components of the solid milk is basically the same as those of thepowdered milk which is the basic ingredient excluding the amount ofwater. Sugar, protein, mineral, and water can be mentioned as thecomponents of the solid milk.

As the fat content in the solid milk, 5%-70% by weight can be mentionedas an example, while 5%-50% by weight is preferable, and 10%-45% byweight is more preferable.

The solid milk of the present inventions may include the emulsified fatand the free fat as the fat. Namely, in the conventional powdered milkand the solid milk, the free fat has been proactively excluded due tothe problems of degrading flavor and floating on water (oil off) whendissolved in heated water. Preferably, the solid milk of the presentinvention proactively includes this free fat for an effective use assubstitute for the lubricant and the like. Thus, the present inventioncan produce good solid milk without using additives. However, too muchfree fat may result in problem of the oil off Therefore, as the free fatcontent in the solid milk of the present invention, 0.5%.4% by weightcan be mentioned, while 0.7%-3% by weight is preferable, and 1%-2.5% byweight is more preferable. This is because a preferable hardness,solubility, and excessive oil off can be controlled as shown in theembodiments which will be described later. It is to be noted that theamount of free fat where the oil off will become problematic depends onthe physicality such as the fat composition and the spherical form offat within the powdered milk used as the basic ingredient, so that theamount of the free fat included in the solid milk may be appropriatelyadjusted within the above-mentioned ranges. It is to be noted that whenmaking the solid milk, even if the same basic ingredient is used, byreducing the compression speed (mobile speed of pestle of thecompression molding machine which is obtained by dividing compressiondisplacement by compression time) in the compression process, forexample, solid milk having a certain degree of hardness while having ahigh porosity can be obtained. When the solid milk is thus made, thefree fat tends to increase. Therefore, in the present invention, thesolid milk may contain more free fat than ordinary solid milk.

When there is much water contained in the solid milk, the storagestability degrades while scarce water makes the solid milk fragile.Therefore, as the water content in the solid milk of the presentinvention, 1%4% by weight can be mentioned, while 2%-3.5% by weight ispreferable.

The shape of the solid milk of the present invention is not specificallylimited as long as the solid milk has a certain size, As the shape ofthe solid milk, column-shaped, elliptical column-shaped, cubic-shaped,rectangular parallelepiped-shaped, plate-shaped, sphere-shaped,polygonal column-shaped, polygonal pyramid-shaped, frustum ofpyramid-shaped, and polyhedron can be mentioned, while column-shaped orquadrangular prism-shaped is preferable from the viewpoint ofportability convenience, it is to be noted that in order to avoidsituation that the solid milk breaks, the corners are preferablychamfered.

The solid milk of the present invention preferably makes a quantity ofmilk to be drank at one time when one to several particles of solid milk(preferably one particle of solid milk) are dissolved in heated water.Therefore, as the volume of the solid milk, 1 cm³-50 cm³ can bementioned, while 2 cm³-30 cm³ is preferable, and 4 cm³-20 cm³ is morepreferable.

The solid milk of the present invention needs to have a certain level ofsolubility. For the solid milk of the present invention under themeasurement condition of solubility which will be described later, onehaving solubility of 60 sec or less can be mentioned, while 45 sec orless is preferable, and 30 sec or less is more preferable. However, evenliquid cannot be obtained if the time is too short, so that thesolubility of 5 sec or more is preferable.

The solid milk of the present invention needs to have a certain level ofstrength in order to avoid as much as possible situation where the solidmilk breaks while being transported, For the solid milk of the presentinvention under the measurement condition of hardness which will bedescribed later, one having hardness of 20 Nor more is preferable. Onthe other hand, from the perspective of solubility, hardness of 300 N orless is preferable. The hardness of the solid milk may be between 30 Nand 200 N inclusive or between 50 N and 100 N inclusive. In thisspecification, the hardness means the hardness under the measurementcondition of the hardness of tablet as will be described later.

2. Manufacturing Process

The method for making the solid milk of the present invention includes acompression step for compressing powdered milk to obtain a solid form ofcompressed powdered milk, a humidifying step for humidifying thecompressed powdered milk obtained by the compression step, and a dryingstep fur drying the compressed powdered milk humidified by thehumidifying step.

2.1Compression Step

The compression step is for compressing a powdered milk to obtain solidform of compressed powdered milk. In the compression step, the powderedmilk is compressed with relatively low pressure to the extent that thepowdered milk can be moved over to a following step, thereby obtainingcompressed powdered milk that secures interstice for the water toinfiltrate. In the compression step, the powdered milk is compressed inorder to fulfill the requirements that compressed powdered milk havingappropriate interstices and having shape retaining attribute. Namely,the porosity in this compression step is closely related to the porosityof the solid milk. Also, if the lubrication of the compressed powderedmilk is scarce, problem of failure in making a tablet that is a part ofthe compressed powdered milk attaches to apparatus such as a tablettingmachine. Moreover, if the shape retaining attribute of the compressedpowdered milk is bad, problem arises in the procedure of making solidmilk that some of the product cannot maintain the shape.

For the basic ingredient of the compression process, preferably onlypowdered milk is used and no additive is substantially added. Thepowdered milk may be purchased commercially or those produced by theknown producing method (such as the producing method as disclosed inJapanese Patent Application Laid-Open Publication Nos. HEI10-262553,HEI11-178506, 2000-41576, 2001-128615, 2003-180244, 2003-245039, and thelike). As the composition of the powdered milk, one similar to that ofthe above-mentioned solid milk can be mentioned. It is to be noted thatas the basic ingredient in the compression process, fat may be added.However, if the fat is added, the fat may cause the oil off. And theadded fat sticks to the surface of the powdered milk, so that theprecision of filling to the mortar is decreased. Therefore, in thecompression stage, the powdered milk which is made to include a targetfree fat content is preferably used.

When the fat content in the powdered milk is large, the compressionforce may be small. On the other hand, when the fat content in thepowdered milk is small, the compression force must be large. Therefore,the use of powdered milk with more fat content satisfies the requirementfor providing appropriate interstices and producing compressed powderedmilk with shape retaining attribute. From such viewpoints, for the fatcontent in the powdered milk, 5%-70% by weight can be mentioned, while5%-50% by weight is preferable, and 10%-45% by weight is morepreferable.

As described above, the powdered milk including the free fat ispreferable. In the present invention, this free fat is effectively usedinstead of lubricant or the like. Accordingly, the present inventionenables production of good solid milk without adding additives. For thefree fat content in the solid milk of the present invention, 0.5%-3% byweight can be mentioned, while 0.7%-2.4% by weight is preferable, and1%-2% by weight is more preferable.

When much water is included in the powdered milk, the shelf lifedegrades, while when the water is less, it becomes fragile (the shaperetention attribute worsens). Therefore, for the content of water in thesolid milk, l%-4% by weight can be mentioned, while 2%-3.5% by weight ispreferable.

In the compression process, the compressed powdered milk is produced bycompression means for compressing the powdered milk to obtain compressedpowdered milk of the solid state. The compression means is notspecifically limited as long as being capable of compressing thepowdered milk to obtain the compressed powdered milk of the solid state.As the compression means, a compression molding machine such as a knowntabletting machine and a compression test apparatus can be mentioned,while the tabletting machine is preferable. It is to be noted that for atabletting machine, those described in Japanese Examined PatentApplication Publication No. SHO33-9237, Japanese Patent ApplicationLaid-Open Publication No. SHO53-59066, Japanese Patent ApplicationLaid-Open Publication Nos. HEI6-218028, 2000-95674, and Japanese PatentNo. 2650493 can be mentioned.

It is to be noted that when using the compression molding machine tocompress powdered object, for example, the powdered object is put in amortar, pound with a pestle to add compression force to the powderedobject, and made into solid state. If the powdered object has scarcelubricity, the situation may occur where the powdered object sticks tothe surface of the pestle. This will not only degrade the quality of theproduct but will require cleaning of the surface of the pestle,resulting in the decrease of the process yield. Therefore, addition oflubricant is performed especially in manufacturing medicine. However,the lubricant is wax that is not very soluble in water. Therefore, it isundesirable to add lubricant to such thing as the solid milk that is fordrinking in a state dissolved in heated water. This is one of thereasons why the manufacturing of the solid milk has been difficult. Thepresent invention, as described above, uses as the lubricant an adequateamount of the free fat that has been regarded as desirable not to begenerated, thereby preventing the situation where the powdered milksticks to the pestle. Moreover, as described above, by obtaining thepowdered milk compressed having an appropriate porosity, it is madepossible to obtain solid milk with an excellent shape retainingattribute. Also, while the addition of disintegrant may cause asituation where sediment is generated, with the method for making thesolid milk of the present invention, the disintegrant is unnecessary, sothat such situation can be effectively avoided.

The environmental temperature in the compression process is notspecifically limited, so that the compression process can be performedin the room temperature. More specifically, for the environmentaltemperature in the compression process, 10° C.-30° C. can be mentioned.For the humidity in the compression process, e.g. 30% RH-50% RH can bementioned. It is preferable in the compression process that thecompression of the powdered milk is performed continuously.

As confirmed by the embodiments that will be described later, whileslowing down the compression speed (movement speed of the pestle in thecompression molding machine) results in longer time for making thepowdered milk solid, solid milk having high porosity as well as acertain degree of hardness can be obtained. On the other hand, whilespeeding up the compression speed enhances the manufacturing ability formaking the powdered milk solid, it is made difficult to obtain thepowdered milk that maintains the hardness. From these viewpoints, forthe compression speed of the tabletting machine, 0.1mm/s-100mm/s can bementioned, while 0.5mm/s-40mm/s is preferable, 2mm/s-20mm/s is morepreferable, and 3mm/s-10 mm/s is further more preferable. In case theporosity is large (e,g. porosity exceeds 50%), by setting thecompression speed to 0.1 mm/s-40mm/s a predetermined degree of hardnesscan be maintained while improving the solubility. On the other hand, incase the porosity is small (e.g. porosity is 50% or less), even when thecompression speed is made about 100 mm/s, the predetermined solubilitycan be obtained while maintaining the predetermined degree of hardness.When the compression speed is slow, although a lot of time is requiredfor making the solid milk, it is preferable, as described above, sincethe predetermined solubility can be obtained while maintaining thepredetermined degree of hardness. For the compression force of thecompression molding machine, 50KPa-30KPa can be mentioned, while 0.1MPa-10 MPa is preferable, 0.1 Mpa-8 MPa is more preferable, 0.1 MPa-5MPa is further preferable, 0.1 MPa-3 MPa is further preferable, and 0.1MPa-1 MPa is especially preferable. It is to be noted that from theviewpoint of shortening the manufacturing time, the compression forcemay be made to more than 1 MPa or 2 Mpa. It is to be noted that thecompression force means the pressure per unit area applied to thepowdered object layer in the maximum compression displacement, which canbe measured by the commercially available load cell and the like. Whilenot specifically limited, 2 mm-4 mm can be mentioned for the compressiondisplacement, and 0.3 s-1 s can be mentioned for the compression time.

When a tabletting machine of single core reciprocating system such as asingle punch tabletting machine is used as the compression moldingmachine, the movement speed of the pestle reciprocating may be adjusted.Also, when a rotary tabletting machine is used as the compressionmoldering machine, the movement speed of the pestle can be adjusted bycontrolling the rotation frequency.

The compression process provided with compression retention time (timeto maintain the maximum compression displacement), is a preferableembodiment of the present invention. As verified by the embodiments thatwill be described later, it is found that compared to one without thiscompression retention time, by providing a predetermined compressionretention time voluntarily even if very small, the porosity of theobtained solid milk decreases and the hardness is increased. Therefore,in order to obtain solid milk having a higher hardness, setting acompression retention time of e.g. 0.1 sec-1 min can be mentioned, while0.1 sec-30 sec is more preferable, 0.1 sec-5 sec is more preferable, and0.1 sec-2 sec is further preferable. When the compression retention timeis long, it requires a lot of time when making solid milk. However, asdescribed above it is made possible to obtain solid milk havingappropriate porosity while maintaining hardness.

2.2 Humidifying Process

The humidifying process is for humidifying the compressed powdered milkobtained by the compression process. By humidifying the compressedpowdered milk, a part of the particle in the vicinity of the surface ofthe compressed powdered milk melts to be bridged. Thus the strength inthe vicinity of the surface of the compressed powdered milk isincreased.

In the humidifying process, the compressed powdered milk can behumidified by the humidifying means for humidifying the compressedpowdered milk. As humidifying means, known humidifying means such ashigh humidity chamber, spray, or steam can be mentioned. Also, ashumidifying method, known humidifying method such as placing the objectunder high humidity condition, misting the object with water by a spray,or spraying steam on the object can be adopted. For humidity in the highhumidity environment, e.g. 60% RH-100% RH can be mentioned, while 80%RH-100% RH is preferable, and 90% RH-100% RH is more preferable. Also,for the time to place the object under the high humidity environment,e.g. 5 sec-1 hr can be mentioned, while 10 sec-20 min is preferable, and15 sec-15 min is more preferable. However, the humidifying time may beappropriately adjusted according to the humidity, temperature, therequired physicality of the solid milk, and the like. The humidifyingtime may be e.g. 1 min-15 min, 1 min-5 min, 5 min-15 min, or 5 min-10min. For the temperature in the method of placing the object under highhumidity environment, e.g. 30° C.-100° C. can be mentioned, while 40°C.-80° C. is preferable. In the humidifying process, under the conditionof higher temperature and higher humidity, the process requires shortertime. As verified by the embodiments that will be described later, bykeeping the humidifying time within certain range, the hardness of theobtained solid milk can be improved.

The amount of water added (hereinafter, also referred to as “humidifyingamount”) to the compressed powdered milk in the humidifying process maybe appropriately adjusted. However, in the present invention, since onlythe powdered milk is basically used as the basic ingredient, asindicated by the embodiment (embodiment 5) and FIG. 3 that will bedescribed later, the following range is preferable as the humidifyingamount. Namely, while the humidifying amount of 0.5% increases thehardness, the humidifying amount of 1% almost doubles the hardness.Thus, the hardness tends to increase as the humidifying amountincreases. On the other hand, the increase of the hardness stops withthe humidifying amount of 2.5% or more. Also, when the humidifyingamount exceeds 3%, the compressed powdered milk dissolves, becomesdeformed, or sticks to the apparatus during transfer. Accordingly, forthe amount of water added to the compressed powdered milk, 0.5%-3% ofthe mass of the compressed powdered milk is preferable, while 1%-2.5% ismore preferable.

2.3 Drying Process

The drying process is for drying the compressed powdered milk that hasbeen humidified by the humidifying step. By the drying step thecompressed powdered milk that has been humidified by the humidifyingstep is dried, so that the surface tackiness is removed, therebyallowing the solid milk to be handled as a manufactured article. As thedrying method in the drying process, known method that can dry thecompressed powdered milk that has been humidified by the humidifyingstep can be adopted. For example, method for placing the object under anenvironment of low humidity and high temperature, or bringing the objectinto contact with drying air and high temperature drying air can bementioned.

For the “humidity” in the method for placing the object underenvironment of low humidity and high temperature, 0% RH-30% RH can bementioned, while 0% RH-25% RH is preferable, and 0% RH-20% RH is morepreferable. Thus, it is preferable to set the humidity as low aspossible. For the “temperature” in the method for placing the objectunder an environment of low humidity and high temperature, 20° C.-150°C. can be mentioned, while 30° C.-100° C. is preferable, and 40° C.-80°C. is more preferable. For the “drying time” in the method for placingthe object under environment of low humidity and high temperature, 0.2min-2 hr can be mentioned, while 0.5 min-1. hr is preferable, and 1min-30 min is more preferable.

As described above, if much water is included in the solid milk, theshelf life is degraded, while if the water is less it becomes fragile.Therefore, in the drying process, it is preferable to control the watercontent in the solid milk to be within 1% below and above (preferablywithin 0.5% below and above) the water content in the powdered milk usedas the basic ingredient by controlling the conditions such as dryingtemperature and drying time.

3. Method of Making Powdered Milk and Solid Milk

The method of making the powdered milk and the solid milk of the presentinvention includes a process of making powdered milk, and a process ofmaking solid milk by using the powdered milk as the basic ingredient. Itis to be noted that a part of the powdered milk made in the process ofmaking powdered milk may be used as powdered milk to be filled directlyin a container. Thus, the powdered milk and the solid milk can beobtained.

3.1 Method of Making Powdered Milk

Details of the manufacturing process of the powdered milk differdepending on the types of the manufactured articles such as powderedskimmed milk, modified milk represented by powdered milk for infants.Basically however, the powdered milk can be made by the process of“basic ingredient(adjustment)→clarification→sterilization→concentration→homogenization)→spraydrying→sieving→filling”. It is to be noted that the size of the powderedmilk after spray drying assumes about 5 μm-150 μm, and the size of thegranulated substance of the powdered milk assumes about 100 μm-500 μm.Also, in the state where the powdered milk and its granulated substanceare mixed, the interstice assumes about 5 μm-150 μm.

Milk can be mentioned as the basic ingredient of the powdered milk. Forthe milk, bovine milk can be mentioned, and more specifically, milk of acow (Holstein, Jersey, etc,), a goat, a ewe, a buffalo, or the like canbe mentioned. The fat content can be adjusted by removing a part of fatfrom the milk by the method of centrifugal separation or the like, Also,the following nutritional components can be added. On the other hand,when making modified powdered milk, the following nutritional componentsare added to the water and mixed to be used.

The powdered milk can be made by the processing the above-mentionedliquid as the ingredient by the known manufacturing method includingprocesses of “clarification”, “sterilization”, “concentration”, “spraydrying”, “sieving”, and “filling”,

For the protein as the basic ingredient of the powdered milk, milkprotein and milk protein fraction such as casein, milk serum protein(α-lactalbumin, β-lactoglobulin, and the like), milk serum proteinconcentrate (WPC), milk serum protein isolate (WPI); animal protein suchas egg protein; plant protein such as soy protein and wheat protein;peptide having the foregoing protein decomposed into variety of chainlengths by enzyme or the like; amino acid such as taurine, cystine,cysteine, arginine, and glutamine may be used alone or by mixture.

For the fat as the basic ingredient of the powdered milk, animal oil andfat such as milk fat, lard, beef fat, fish vegetable oil such as soyoil, canola oil, corn oil, coconut oil, palm oil, palm kernel oil,safflower oil, cottonseed oil, linseed oil, and MCT; or fractional oil,hydrogenated oil, or ester exchanged oil of the foregoing oil may beused alone or by mixture.

For the carbohydrate as the basic ingredient of the powdered milk,lactin, simple sugar, glucose, malt sugar, oligosaccharide such asgalacto-oligosaccharide, fructo-oligosaccharide, lactulose,polysaccharide such as farina, soluble polysaccharide, and dextrin, orartificial sweetener may be used alone or by mixture.

In addition, vitamin group, mineral group, aroma chemical, flavoringsubstance, or the like may be added as the basic ingredient of thepowdered milk.

3.1.1. Clarification Process

The clarification step is for removing microscopic foreign substanceincluded in cow milk or the like by known means such as centrifugalseparator, filter, or the like.

3.1.2. Sterilization Process

The sterilization process is for deadening microbe such as bacteriaincluded in cow milk or the like. The deadening temperature and holdingtime in the sterilization process vary depending on the types of thepowdered milk, and conditions related to the known sterilization can beadopted.

3.1.3. Concentration Process

The concentration process is an arbitrary process for preparatorilyconcentrating milk or the like before the spray drying process whichwill be described later, and known means such as vacuum evaporative canand conditions can be adopted.

3.1.4. Homogenization Process

The homogenization process is an arbitrary process for homogenizing thesize of solid component such as fat globule distributed within cow milkor the like to fixed size, and known means and conditions for applyinghigh pressure to the processed liquid so as to pass the processed liquidthrough a narrow gap.

3.1.5. Spray Drying Process

The spray drying process is for obtaining fine particles by evaporatingthe water within the concentrated milk. A known means such as spraydryer and known condition can be adopted.

3.1.6. Sieving Process

The sieving process is for removing particles whose diameter is largesuch as hard-packed powder by passing the fine particles obtained by thespray drying process through sieves for particle size regulation.

3.1.7. Filling Process

The filling process is for filling the powdered milk in bags, cans, andthe like.

For the method of making the powdered milk and the solid milk of thepresent invention, the above-mentioned method of making solid milk maybe adopted after making the powdered milk as mentioned above. Namely,the above-mentioned compression process may be performed using thepowdered milk having passed through the above-mentioned sieving processas the basic ingredient.

4. Usage of Solid Milk

The solid milk of the present invention is generally dissolved in heatedwater for drinking. More specifically, after pouring heated water in acovered container, particles of the solid milk of the present inventionas required are put in. Then, preferably the container is lightly shakenin order to quickly dissolve the solid milk for drinking in the state ofappropriate temperature.

While embodiments are shown hereinafter and the feature of the presentinvention will be described, the present invention is not limited tothese embodiments. In the following description, methods for evaluatingitems to be evaluated in the embodiments will be described beforedescribing reference examples and embodiments.

TEST EXAMPLE 1 Porosity Measurement for Solid Milk

The porosity of the solid milk is obtained by the following equation:

Porosity(%)=(1−W/PV)×100

W: weight of solid substance (g)

P: density of solid substance measured using Beckmann pneumaticdensimeter (g/cm³)

V: cubic measure obtained by measuring diameter and thickness of thesolid substance with a micrometer to be calculated (cm³)

TEST EXAMPLE 2 Measurement of Free Fat Content

The free fat content is measured as follows: Firstly, while taking carenot to mash the solid milk, the solid milk was finely cut into pieceswith cutter and smashed up (smash up process). Thereafter, the smashedup solid milk was passed though 32 mesh sieve (sieving process). Takingthe sample after having passed through the sieving process, the free fatcontent was measured according to the method described in ‘Determinationof Free Fat on the Surface of Milk Powder Particles’, Analytical Methodfor Dry Milk Products, A/S NIRO ATOMIZER (1978), It is to be noted thatwith this method, the free fat content is indicated by % by weight ofthe fat extracted with an organic solvent (e.g. n-hexane or carbontetrachloride) by shaking at fixed speed for fixed time.

TEST EXAMPLE 3 Hardness Measurement

The hardness of the solid milk (tablet hardness) was measured using ahardness tester manufactured by Okada Seiko Co., Ltd. Namely, load wasapplied in the direction where the area of the broken-out section of thesample is minimized to measure the load upon breaking.

TEST EXAMPLE 4 Solubility Measurement

The solubility of the solid milk was measured as follows: Firstly, 100ml of water was poured into a capped glass pot of 200 ml and heated to50° C. A particle of solid milk was put into this water, immediatelyshaken, and the time until the solid milk completely disappears wasmeasured. The shaking condition was 1.5 laps/s and amplitude of 30 cm.

TEST EXAMPLE 5 Floating Oil Measurement

The floating oil (oil off) was measured as follows: Firstly, 50 ml ofwater at 50° C. in 100 ml beaker was prepared. A particle of solid milkwas put into the water, and completely dissolved. After leaving at restfor 2 hours, presence of oil droplets was determined by visualobservation.

TEST EXAMPLE 6 Peroxide Value Measurement

The peroxide value is measured as follows: Hot water of 60° C.-70° C.was added to the sample, mixed well until dissolved to obtain emulsifiedliquid. Nonionic surface-active agent (polyoxy octyl phenol ether) andsodium tripolyphosphate were added thereto and after being demulsified,centrifugalized into oil layer and water layer. The oil layer was takenout and measured using an iodine titration technique (Japan Oil ChemisesSociety, Kijyun Yushi Bunnseki Shiken-hou (Reference oil analysis andtest technique, peroxide value (chloroform method)). The measured valueaccording to this technique was indicated by mile equivalent amount ofiodine for the sample of 1 kg when iodide of potash is added to thesample. This may be used as indication of oxidation degradation.

TEST EXAMPLE 7 Flavor Test

For the flavor test, the sample was dissolved in water of 50° C. so thatthe sample assumes 14% by weight of density and then drunk by tenpanelist who rate from the palatability viewpoint ranging between sevendegrees from 1 to 7 (4 is the mid-value indicating averagepalatability), and the average thereof was used for the evaluation.

REFERENCE EXAMPLE 1 Making Powdered Milk

The powdered milk including various components was made from liquidwhich was mixture of fat, sugar, protein, milk, and mineral group addedto water and processed in the process order of homogenization,concentration (evaporation), and spray drying.

Embodiment 1 (Relationship Between Porosity, Solubility, and Strength)

The powdered milk obtained by the manufacturing method of the referenceexample (including 25% by weight of fat, 58.3% by weight of sugar, 11.7%by weight of protein, mineral, water, etc.) was compressed and molded bya universal tester Autograph (manufactured by Shimadzu Corporation)under conditions of compression force of 0.5 MPa-30 MPa and pestledescending speed of 10 mm/min. Thereafter, left in a temperature andhumidity chamber (manufactured by TABAI ESPEC) under conditions of 40°C. and 95% RH for 5 minutes. Then dried with air oven (manufactured byYamato Scientific Co., Ltd) at 40° C. for 30 minutes. Thus, solid milkwith diameter of 25 mm and weight of approximately 5 g was obtained. Thepowdered milk used as the basic ingredient and the solid milk obtainedtherefrom was evaluated by test examples 1-5. The result thereof isshown in Table 1. Also, the relationship between the porosity and thedissolution time in the Table 1 is shown in FIG. 1. The relationshipbetween the compression force and the free fat in the Table 1 is shownin FIG. 2.

TABLE 1 Compression force and properties of solid milk Compression force(MPa) 0 0.5 1 2 5 7.5 10 15 20 30 Porosity (%) 62.7 54.8 51.9 48.6 39.535.4 31.8 30.1 25.7 19.3 Free fat (%) 0.46 0.69 0.77 0.69 1.29 1.80 2.392.66 3.57 5.75 Hardness before 0 1.5 5.1 8.2 32.9 53.3 68.6 83.8 116.5181.7 humidification (N) Hardness (N)

18.3 30.2 40.3 81.8 106.0 140.3 154.4 185.3 291.0 Solubility (s) 10 1010 10 20 40 50 110 278 490 Oil off (—)

± ± ± ± ±

Oil off evaluation

 No floatage ± Microscopic floatage (smaller than 0.5 mm) not so much ascausing practical trouble is observed

 Floatage (larger than 0.5 mm) in the form of oil droplets is observed

It is seen from FIG. 1 that the porosity and the dissolution time arecorrelated. Also, it is seen from FIG. 1 that the dissolution timechanges rapidly in the vicinity of 30% porosity. The practicaldissolution time for the solid milk to be dissolved for drinking ispreferably within 120 sec and more preferably within 60 sec. As shown inTable 1, the solid milk with the porosity of 25.5% (compression force of20 MPa) required 278 sec (approximately 4.6 min) to dissolve. Therefore,this solid milk is not practical. The solid milk with the porosity of30.1% (compression force of 15 MPa) dissolved in 110 sec. Also, thesolid milk with the porosity of 31.8% (compression force of 10 MPa)dissolved in 50 sec. Therefore, it is found that from the solubilitypoint of view, the porosity of 30% or more and the compression force of15 MPa or less are preferable.

Also, it is seen from Table 1 that when the compression force exceeds 20MPa, oil droplets are observed on the surface of water, so that there isproblem of oil off. When the compression force is 15 MPa or less, theoil off is not so much as causing practical trouble. Namely, from theoil off point of view, it is seen that the porosity of 30% or more andthe compression force of 15 MPa or less are preferable. Meanwhile, it isseen from FIG. 2 that the compression force and the generated amount offree fat are correlated, so that the amount of free fat can becontrolled by controlling the compression force.

The compression molded substance also increased the hardness byhumidifying and drying process. The hardness required for transportationand handling by the user is about 20 N, which was achieved by moldingwith compression force of 1 MPa, and performing humidification anddrying process.

It is seen that for the evaluation items including the solubility, thehardness before and after the humidification and drying, and the oiloff, the compression condition with the porosity of about 30%-55% andthe compression force of about 0.5 MPa-15MPa is appropriate.

Embodiment 2

(Using Powdered Milk of Powder or Granulated Powder with Different FatContent)

In this embodiment, except that the powdered milk with the fat contentof 5%-40% by weight is molded with the compression force of 5 MPa, solidmilk with diameter of 25 mm and weight of approximately 5 g was obtainedby the same process and condition with those of the embodiment 1. Thesewere evaluated by the test examples 1-5. The result thereof is shown inTable 2. It is to be noted that the evaluation items of the oil off isthe same as those of the embodiment 1.

TABLE 2 Fat content and properties of solid milk Fat content (%) 5 10 1825 30 40 Powdered milk Shape granule granule granule granule powderpowder as ingredient Free fat (%) 0.03 0.28 0.46 0.46 1.33 1.48 MoldedPorosity (%) 45.0 42.2 41.5 39.5 36.3 31.0 substance Free fat (%) 0.110.51 0.84 1.29 3.02 3.93 Hardness before 0 4.2 12.5 32.9 17.4 30.0humidification (N) Hardness (N) 18.1 17.6 46.0 81.8 25.9 83.0 Solubility(s) 30 20 30 20 40 50 Oil off (—)

± ±

±

One that used the powdered milk with the fat content of 5% by weightincluded some of the compressed and molded substance beforehumidification and drying process (free fat of 0.11%) whose hardness islow, so that transition to the next process has been a little difficult.One that used the powdered milk with the fat content of 10% by weight ormore yielded the compressed and molded substance of favorableperformance regardless of the presence of granulation.

Thus, with the powdered milk including the fat to some extent, thecompressed and molded substance provided with the conflicting, elementsof hardness and fast solubility can be obtained without adding specificadditive by adjusting the compression force, the porosity, and theamount of free fat to the limitation of the present invention.

Embodiment 3 (Effect of Free Fat)

In the embodiment 2, when the powdered milk with the fat content of 5%by weight was used, some of the compressed and molded substance beforehumidification and drying process had low hardness. Butter oil(manufactured by Corman) of (i) 0.5% by weight, (ii) 1.0% by weight, and(iii) 2.0% by weight were added to the powdered milk with the fatcontent of 5% by weight, mixed well, and then compressed and moldedunder the conditions shown in the embodiment 2 to examine the hardnessincreasing effect of the free fat, The result thereof is shown in Table3.

TABLE 3 Amount of additional fat and properties of solid milk Amount ofbutter oil added (%) 0 0.5 1 2 Porosity (%) 45.9 45.6 45.6 44.7 Hardnessbefore humidification (i) (N) 0 0 0 0 Hardness before humidification(ii) (N) 0 7.2 7.3 7.3 (i) Compression molded immediately after addingbutter oil (ii) Compression molded after adding butter oil and preservedin hermetic container for 2 days

While all of those that were compressed and molded immediately afteradding the butter oil had extremely low hardness, those that werecompressed and molded after a lapse of two days had the hardness ofapproximately 7 N. The one without addition of butter resulted inextremely low hardness regardless of the neglected time. Since there isno big difference between the porosities of these compressed and moldedsubstances, it is seen that the addition of oil helped to enhance theshape retaining attribute.

From the above-mentioned result, it is presumed that mere addition ofthe fat does not contribute to the increase of hardness, but the fatexisting in the state of having penetrated inwards from the surface ofthe particle of the powdered milk with the lapse of time helps toenhance the hardness. It is to be noted that the effect of enhancinghardness was not obtained with the powdered milk having solid oil (palmhardened oil, melting point of 58° C., manufactured by Taiyo YushiCorp.) that is waxy at room temperature added instead of the butter oilthat is liquid at room temperature.

Generally, solid oil (wax) is known to have the lubricating effect forreducing friction upon compression and molding, and is used extensivelyfor this purpose. However, when the compression and molding under lowpressure is required in order to secure an interstice as in the presentinvention, one having both effects of adding lubricity and theenhancement of shape retaining attribute is useful. While addition offat that is liquid at room temperature is effective, a process for theaddition is added, and the powder to which the liquid fat is added losesthe fluidity, thereby decreasing the mortar filling ability. Therefore,releasing the fat essentially included in the milk fat upon compressionand molding required when compressing and molding the fat is extremelypractical.

Embodiment 4 (Productivity Verification)

The powdered milk obtained by the manufacturing method of the referenceexample (including 25% by weight of fat, 58.3% by weight of sugar, 11.7%by weight of protein, mineral, water, etc.) is compressed and moldedcontinuously for 1 hour by a single punch tabletting machine(manufactured by Okada Seiko Co., Ltd.) under conditions of compressionforce of 5 MPa and 20 tablets/min (1200 tablets/h). Thereafter, left ina temperature and humidity chamber (manufactured by TABAI ESPEC) underconditions of 40° C. and 95% RH for 5 minutes. Then dried with an airoven (manufactured by Vamato Scientific Co., Ltd.) at 40° C. for 30minutes. Thus, solid milk with diameter of 25 mm and weight ofapproximately 4.2 g was obtained.

During 1 hour of continuous tabletting, no tabletting failure due to thesticking of powder to the mortar and pestle was observed, and theoperation was not interrupted. The result of the continuous tablettingexperiment is shown in Table 4. The compressed and molded substance hasstrength of 10 N, and there was no trouble such as losing shape upontransition to the humidifying process. The milk solid substancemanufactured through the drying process had the solubility of 30 sec andless, and sufficient hardness of 92.5 N. Also, no oil off was observed,and the flavor was not different from the powdered milk used as thebasic ingredient. It is to be noted that the porosity of this milk solidsubstance is 36.3% and the free fat is 0.54%.

TABLE 4 Continuous tabletting experiment Powdered milk as ingredientSolid milk Porosity (%) 36.3 Hardness before humidification (N) 10.0Hardness (N) 92.5 Solubility (s) 10 30 Free fat (%) 0.09 0.54 Oil off(—)

Flavor (—) 4.10 4.10

Embodiment 5 (Examination of Humidification Condition)

The powdered milk (including 25% by weight of fat, 58.3% by weight ofsugar, 11.7% by weight of protein, mineral, water) is compressed andmolded by a universal tester Autograph (manufactured by ShimadzuCorporation) under conditions of compression force of 5 MPa andcompression speed of 10 mm/min is used as sample to examine thehumidification condition

The sample is left for fixed time under 80° C. and 100% RH (using CombiOven, manufactured by FUJIMAK) or under 40° C. and 95% RH (usingtemperature and humidity chamber, manufactured by TABAI ESPEC). Theweight of water increased by the humidification was obtained bymeasuring weight before and after the humidification. Thereafter, thesample was dried with an air oven (manufactured by Yamato ScientificCo., Ltd.) at 40° C. for 30 minutes and the strength was measured, Therelationship between the humidification time and the strength in theembodiment 5 is shown is FIG. 3 while the relationship between thehumidification amount of water and the hardness is shown in FIG. 4.Also, the relationships between the humidification time, thehumidification weight (%), and the hardness (N) after the drying arerespectively shown in Tables 5-1 and 5-2.

TABLE 5-1 Condition: Temperature 80° C. 

 100% RH Humidifying time (s) 0 5 10 15 30 60 90 120 180 Humidify- 0 0.50.5 0.8 1.1 1.5 2 2.5 2.8 ing weight (%) Hardness 12.7 2.5 23 31.3 56.596.7 103 119 114 after drying (N)

TABLE 5-2 Condition: Temperature 40° C. 

 95% RH Humidifying time (s) 0 60 120 180 300 600 900 Humidifying weight0 0.5 0.7 0.9 1.2 1.6 1.9 (%) Hardness after drying 12.7 17.3 25 29.539.5 64.8 78.2 (N)

According to FIG. 3, it is seen that the solid milk having higherstrength can be obtained in short time by processing under highertemperature. Also, according to FIG. 4, it is seen that thehumidification of 0.5% by weight yields the strength increasing effect.Also, the strength almost doubles with the humidification ofapproximately 1 by weight, so that the strength tends to increase withthe increase of the humidification weight. The increase of strengthstops when the humidification weight exceeds 2.5% by weight.

Embodiment 6 (Long-Term Storage Stability)

The solid milk made by the compression force of 5 MPa of the embodiment1 and the powdered milk used as the basic ingredient are put in aluminumbags and preserved under the condition of 30° C. for three months toexamine the items of the dissolution time, the hardness, the free fat,the peroxide value, the oil off, and the flavor according to the testexamples. The result thereof is shown in Table 6. It is seen from Table6 that the items of the dissolution time, the strength, the free fat,the oil off, and the flavor had no difference from the default values.As for the peroxide value, the solid milk showed comparable value withthat of the powdered milk used as the basic ingredient. Thus, the milksolid substance made by the method of the presentinvention has excellentlong-term storage stability.

TABLE 6 Long-term storage stability at 30° C. Powdered milk Solid milk(ingredient) 3 months 3 months Examined item start later start laterFree fat (%) 1.26 1.39 0.54 0.59 Peroxide value (meq/kg) 0.08 0.95 0.120.78 Oil off (—) ± ± ± ± Flavor (—) 4.08 4.09 4.00 3.91 Dissolution time(s) 30 30 Hardness (N) 42 43

Embodiment 7

(Examination of Solid Milk Physicality with Tabletting Machine)

By using the basic ingredients which will be described later, how thesolid milk obtained is influenced by the compression force in thecompression process and the humidifying time in the humidifying step onthe physicality (especially the relationship between the porosity andstrength or the dissolution time) is examined. The composition of thebasic ingredient is; 25.9% of fat, 11.8% of protein, 57.2% ofcarbohydrate, 2.3% of ash, and 2.8% of water. It is to be noted that thesolid milk manufactured is column-shaped whose diameter is 30 mm, andthe weight per particle is made 5 g. Also, as the compression moldingmachine, a single punch tabletting machine (manufactured by Okada SeikoCo., Ltd.) is used with the compression speed of 10 mm/s. If nototherwise specified, the humidifying process is at 60° C. and 96% RH for3 minutes. It is to be noted that in some cases, the humidifying timewas made 4 minutes or 5 minutes. Also, the drying process is at 80° C.for 5 minutes. The result thereof is shown in Table 7. From Table 7, itis seen that the smaller the compression three, the lesser the free fat,and the strength of the obtained solid milk decreased, but the porosityincreases. It is also seen that when the solid milk is manufactured witha low compression force (e.g. 0.14 MPa-4.95 MPa, especially 0.14MPa-1.34 MPa) the solid milk having high porosity but maintainingcertain level of strength can be obtained. Moreover, it is seen that bykeeping the humidifying time within predetermined range, the strength ofthe obtained solid milk increases. In the embodiment 7, the dissolutiontime of the solid milk is 60 sec when the target porosity is 30%, 20 secwhen the target porosity is 40%, and 10 sec when the target porosity is50% or more. The dissolution time of the solid milk could be remarkablyshortened when the compression speed is made equal to or lower than 10mm/s. In order to obtain solid milk with the porosity more than 50% andless than 60%, it is considered that the compression force is only to becontrolled to approximately 0.1 MPa-0.3 MPa.

TABLE 7 Relationship between porosity and physicality Target porosity[%] 30 35 40 45 50 55 55¹⁾ 60 60²⁾ Compression force 10.62 7.08 4.952.56 1.34 0.35 0.35 0.14 0.14 [MPa] Porosity [%] 29.6 35.8 39.4 44.148.8 54.0 53.9 58.0 57.2 Free fat [%] 3.00 2.22 1.68 1.17 0.91 0.75 0.750.73 0.73 Hardness before 51.3 29.8 18.6 8.6 3.7 1.1 1.1

hardening [N] Hardness [N] 265.2 196.1 133.3 65.3 37.7 21.0 30.0 16.420.2 Dissolution time 60 30 20 15 10 10 10 10 10 [s] ¹Hardeningcondition: humidifying time of 4 min ²Hardening condition: humidifyingtime of 5 min

Embodiment 8 (Influence of Compression Speed on Strength of Solid Milk,Quadrangular Prism-Shaped Solid Milk)

In order to examine the influence of the compression speed on theobtained solid milk, the solid milk was made by changing the compressionspeed. Namely, by using a single punch tabletting machine (manufacturedby Okada Seiko Co., Ltd.) under conditions various compression speeds,the quadrangular prism-shaped solid milk (22 mm×35 mm×10 mm) isobtained. The composition of the basic ingredient is; 25.9% of fat,11.8% of protein, 57.2% of carbohydrate, 2.3% of ash, and 2.8% of water.It is to he noted that adjustments were made so that the porosity of theobtained solid milk assume approximately 45%, 50%, and 55%.

FIGS. 5A-5C are graphs showing the physicality of the solid milkobtained by the embodiment 8. FIG. 5A is a graph showing therelationship between the compression speed and the strength of theobtained solid milk, FIG. 5B is a graph showing the relationship betweenthe compression speed and the free fat. FIG. 5C is a graph showing therelationship between the strength and the free fat of the solid milk. Itis seen from FIG. 5A that even if the porosity is the same, the smallerthe compression speed, the solid milk with higher strength can beobtained. It is seen from FIG. 5B that by controlling the compressionspeed, the amount of the free fat can be controlled. It is seen fromFIG. 5C that the strength and the free fat are correlated. Accordingly,it can be said that even with the solid milk of the same porosity, inorder to increase the strength, it is effective to reduce thecompression speed and intentionally generate the free fat. Specificallyspeaking, it is seen that in order to increase the strength of the solidmilk, it is only necessary to make the compression speed e.g.0.1mm/s-100mm/s, preferably 1 mm/s-80mm/s, and more preferably 2 mm/s-60mm/s. Moreover, while controlling the amount of the free fat is animportant factor for the solid milk of the present invention, especiallyfor the solid milk with porosity of 50% or less, the amount of the freefat can be effectively increased by controlling the compression speedequal to or below 40 mm/s.

Embodiment 9 (Influence of Compression Speed on Strength of Solid Milk,Column-Shaped Solid Milk)

In order to examine the influence of the compression speed on theobtained solid milk, the solid milk was made by changing the compressionspeed. Namely, by using a single punch tabletting machine (manufacturedby Okada Seiko Co., Ltd.) under conditions various compression speeds,the column-shaped solid milk (diameter of 30 mm×10 mm) is obtained. Thecomposition of the basic ingredient is; 18% of fat, 15% of protein,60.1% of carbohydrate, 4.1% of ash, and 2.8% of water. It is to be notedthat adjustments were made so that the porosity of the obtained solidmilk assume approximately 45%, 50%, and 55%.

FIGS. 6A and 6B are graphs showing the physicality of the solid milkobtained by the embodiment 9. FIG. 6A is a graph showing therelationship between the compression speed and the strength of theobtained solid milk. FIG. 6B is a graph showing the relationship betweenthe compression speed and the free fat. It is seen from FIG. 6A thateven if the porosity is the same, the smaller the compression speed, thesolid milk with higher strength can be obtained. It is seen from FIG. 6Bthat by controlling the compression speed, the amount of the free fatcan be controlled. Accordingly, it can be said that even with the solidmilk of the same porosity, in order to increase the strength, it iseffective to reduce the compression speed and intentionally generate thefree fat. Specifically speaking, it is seen that in order to increasethe strength of the solid milk, it is only necessary to make thecompression speed e.g. 0.1 mm/s-100 mm/s, preferably 1 mm/s-80 mm/s, andmore preferably 2 mm/s-60 mm/s. Under the conditions of the embodiment9, especially for the case where the porosity is 45% or below(specifically the case where the porosity is 40%), the strength isremarkably increased by making the compression speed 10 mm/s-30 mm/s.Moreover, while controlling the amount of the free fat is an importantfactor for the solid milk of the present invention, especially for thesolid milk with porosity of 50% or less, the amount of the free fat canbe effectively increased by controlling the compression speed equal toor below 40 mm/s.

Embodiment 10

In this embodiment, a rotary tabletting machine (manufactured by KikusuiSeisakusho Ltd.) is used to examine the relationship between thecompression speed and the strength of the solid milk obtained. Thecomposition of the basic ingredient is; 25.9% of fat, 11.8% of protein,57.2% of carbohydrate, 2.3% of ash, and 2.8% of water. The compressionspeed was adjusted by changing the rotational frequency of the rotarytabletting machine. FIG. 7 shows the relationship between thecompression speed and the strength of the solid milk when the porosityof the solid milk is made 43%. From FIG. 7, it is seen that in the sameway as in the embodiment 8 and embodiment 9, the smaller the compressionspeed, the solid milk with the higher strength can be obtained. In orderto reduce the compression speed in the rotary tabletting machine, therotational frequency is required to be reduced, so that themanufacturing capacity is decreased. Therefore, pressure rollers forupper and lower pestles of the rotary tabletting machine are removed andlinear tracks of 15 cm in length (pressure rails) are provided thereinto sandwich the upper and lower pestles. The rail on the side of thelower pestle is provided with a lean of 0.82° . It is structured thatwhen the lower pestle passes between the rails, the lower pestle rises 2mm, thereby enabling a slow compression and molding. By using thesepressure rails, it is made possible to slow down the compression speedwithout reducing the rotational frequency and to increase the strengthof the solid milk. The solid milk is obtained by using this pressurerails to make the rotational frequency 30 rpm and 40 rpm. Therelationship between the compression speed and the strength of the solidmilk obtained by using these pressure rails is shown as two points inthe area enclosed in a circle in FIG. 7.

Embodiment 11 (Influence of Compression Speed and Compression RetentionTime on Porosity and Strength of Solid Milk)

In this embodiment, the compression speed, the compression retentiontime (time to retain the maximum compression displacement) as well asthe porosity and the hardness of the obtained solid milk are examined.The composition of the basic ingredient is; 25.9% of fat, 11.8% ofprotein, 57.2% of carbohydrate, 2.3% of ash, and 2.8% of water. It is tobe noted that the manufactured solid milk is quadrangular prism-shaped(22 mm×35 mm×12 mm) and the weight per particle is made 5.5 g. Also, thecompression and molding machine used has features such as a hydrauliccylinder driven type, capable of setting displacement of upper and lowerpestles, capable of changing compression speed, capable of settingcompression retention time. In the compression process, a predeterminedbasic ingredient is put in the mortar, preliminarily compressed with theupper pestle, then compressed and molded by fixing the displacement ofthe lower pestle to 4 mm, while adjusting the porosity by thedisplacement of the upper pestle. The humidification process wasperformed at 60° C. and 96% RH to be held for 3 minutes. The dryingprocess was performed at 80° C. to be held for 5 minutes. The resultthereof is shown in Table 8. In Table 8, the total time is the sum ofthe compression time and the holding time. It is seen that when there isno compression retention time, the smaller the compression speed gets,the larger the hardness of the solid milk gets. In the cases where thecompression retention time is set, in each compression speed, as thecompression retention time increases, the porosity of the solid milk isdecreased while the hardness is increased. Each of the hardening treatedresult of the thregoing achieved the predetermined hardness and thedissolution time. Accordingly, it is seen that by appropriatelycombining the compression speed and the compression retention time, thetotal time for the compression molding, the porosity and the hardness ofthe solid milk can be controlled.

TABLE 8 Relationship between compression condition and physicality ofsolid milk Compression condition Before After hardening Displacement ofCompression Compression Retention Total hardening Dissolution Free upperpestle speed time time time Porosity Hardness Porosity Hardness time fat(mm) (mm/s) (s) (s) (s) (%) (N) (%) (N) (s) (%) 4.0 3.6 1.1 0.0 1.1 52.91.2 53.3 26.4 15 0.80 0.3 1.4 51.3 2.0 50.7 36.2 15 0.85 1.0 2.1 50.92.7 6.0 0.7 0.0 0.7 52.4 1.0 52.4 30.4 15 0.77 0.1 0.8 51.3 1.7 50.240.9 15 0.86 0.3 1.0 50.8 2.1 50.0 37.8 15 0.89 0.5 1.2 50.8 2.6 1.0 1.750.6 2.8 50.0 35.7 15 0.89 2.0 2.7 50.4 3.0 13.3 0.3 0.3 0.6 50.6 2.10.7 1.0 50.5 2.4 36.4 0.1 0.0 0.1 50.8 nd 0.3 0.4 50.5 0.9 1.0 1.1 50.21.1 6.0 9.1 0.4 0.0 0.4 46.4 5.4 45.7 62 20 1.11 0.1 0.5 46.0 6.3 0.30.7 45.8 6.6 45.2 63.9 20 1.08 1.0 1.4 45.8 7.2 nd: rupture pointundetectable

Embodiment 12 (Relationship Between Volume of Solid Milk and Hardness orDissolution Time)

In this embodiment, solid milk with various volumes is manufactured by asingle punch tabletting machine (manufactured by Okada Seiko Co., Ltd.).The relationship between the shape, the volume, the hardness, and thedissolution time is shown in Table 9. The composition of the basicingredient is; 18% of fat, 15% of protein, 60.1% of carbohydrate, 4.1%of ash, and 2.8% of water. It is seen from Table 9 that the solid milkhaving the porosity of the present invention accomplishes thepredetermined strength and the dissolution time even if the shape or thevolume differs.

TABLE 9 Relationship between volume and physicality of solid milk Thick-Hard- Weight ness Volume Porosity ness Dissolution Shape [g] [mm] [cm³][%] [N] time [s] column- 1.025 9.50 1.7 51.1 34.7 10 shaped (diameter 15mm) column- 5.100 11.80 8.3 51.1 39.6 15 shaped (diameter 30 mm) column-7.547 17.56 12.4 51.3 41.2 20 shaped (diameter 30 mm) cubic- 9.977 20.3216.6 51.9 56.2 20 shaped (24 × 34 mm)

The solid milk of the present invention when actually manufactured, isfound to be suitable to be manufactured and marketed as commercialproducts, the solid milk and the method of making the same according tothe present invention can be used in the foods industry such asalternative for the powdered milk and the method of making the same.

1. Solid milk with a porosity of 30% to 60%, comprising 1 wt % to 2.5 wt% of free fat,
 2. The solid milk according to claim 1, wherein the solidmilk comprises 1 wt % to 4 wt % of water.
 3. The solid milk according toclaim 1, wherein a volume of the solid milk is 1 cm³ to 50 cm³.
 4. Thesolid milk according to claim 1, wherein only powdered milk is used as abasic ingredient.
 5. A method of making solid milk, comprising:compressing powdered milk to obtain a solid form of compressed powderedmilk; humidifying the compressed powdered milk obtained by thecompressing; and drying the compressed powdered milk humidified by thehumidifying, wherein the compressing is performed by using a compressionmolding machine that compresses the powdered milk, with a compressionspeed of 0.1 mm/s to 100 mm/s and a compression force of 50 KPa to 30MPa.
 6. The method according to claim 10, wherein the compression speedis 0.1 mm/s to 40 mm/s.
 7. The method according to claim 10, wherein thecompression speed is 3 mm/s to 10 mm/s.
 8. The method according to claim10, wherein a retention time in the compressing is 0.1 second to 1minute.
 9. The method according to claim 10, wherein the powdered milkcomprises 0.5 wt % to 3 wt % of free fat.
 10. The method according toclaim 10, wherein the humidifying is performed by placing the compressedpowdered milk in an environment of 60% RH to 80% RH for 5 seconds to 1hour.
 11. The method according to claim 10, wherein an amount ofmoisture added to the compressed powdered milk by the humidifying is 0.5wt % to 3 wt % of the compressed powdered milk.